Water
Contamination Sources and Methods of Treatment
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- ACIDIC
WATER
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Source
- Acidic waters usually attain their acidity from the
seepage of acid mine waters, or acidic industrial wastes.
Acid mine waters are frequently too low in pH
to provide suitable drinking water even after neutralization
and Treatment.
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Treatment
- Acidic water can be corrected by injecting soda ash or caustic
soda (sodium hydroxide) into the water supply to raise the
pH. Utilization of these two chemicals slightly increases
the alkalinity in direct proportion to the amount used. Acidic
water can also be neutralized up to a point by running it
through calcite, corosex or a combination of the two. The
calcite and the corosex both neutralize by dissolving and
they add hardness to the water as the neutralization takes
place; therefore, they both need to be replenished on a periodic
basis.
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- ALUMINUM
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Source
- Aluminum (Al+3) is an abundant metal in the Earth's surface,
but its solubility in water is so low that it is seldom a
concern in municipal or industrial water systems. The majority
of natural water contains from 0.1 ppm up to 9.0 ppm of Aluminum,
however the primary Source of Aluminum in drinking water comes
from the use of aluminum sulfate (alum) as a coagulant in
water Treatment plants. The total dietary exposure to aluminum
salts averages around 20 mg/day. Aluminum is on the US EPA's
Secondary Drinking Water Standards list with suggested levels
of 0.05 - 0.2 mg/l; dependent on case-by-case circumstances.
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Treatment
- Aluminum can be removed from water by a cation exchanger
but hydrochloric acid or sulfuric acid must be used for regeneration
to remove the aluminum from the resin. While this is suitable
for an industrial application it is not recommended for domestic
use unless it is in the form of a cation exchange tank. Reverse
Osmosis will reduce the aluminum content of drinking water
by 98 + %. Distillation will reduce the aluminum content of
water by 99 + %. Electrodialysis is also very effective in
the reduction of aluminum.
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- AMMONIA
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Source
- Ammonia (NH3) gas, usually expressed as Nitrogen, is extremely
soluble in water. It is the natural product of decay of organic
nitrogen compounds. Ammonia finds its way into surface supplies
from the runoff in agricultural areas where it is applied
as fertilizer. It can also find its way to underground aquifers
from animal feed lots. Ammonia is oxidized to nitrate by bacterial
action. A concentration of 0.1 to 1.0 ppm is typically found
in most surface water supplies, and is expressed as N. Ammonia
is not usually found in well water supplies because the bacteria
in the soil converts it nitrates. The concentration of Ammonia
is not restricted by drinking water standards. Since Ammonia
is corrosive to copper alloys it is a concern in cooling systems
and in boiler feed.
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Treatment
- Ammonia can be destroyed chemically by chlorination. The
initial reaction forms chloramine, and must be completely
broken down before there is a chlorine residual. Organic contaminants
in the waste stream will be destroyed by the chlorine before
it will react with the ammonia. Ammonia can also be removed
by cation exchange resin in the hydrogen form, which is the
utilization of acid as a regenerant. Degasification will also
remove Ammonia.
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- ARSENIC
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Source -
Arsenic (As) is not easily dissolved in water, therefore,
if it is found in a water supply, it usually comes from mining
or metallurgical operations or from runoff from agricultural
areas where materials containing arsenic were used as industrial
poisons. Arsenic and phosphate easily substitute for one another
chemically, therefore commercial grade phosphate can have
some arsenic in it. Arsenic is highly toxic and has been classified
by the US EPA as a carcinogen. The current MCL for arsenic
is 0.05 mg/l which was derived from toxicity considerations
rather than carcinogenicity.
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Treatment
- If in an inorganic form, arsenic can be removed or reduced
by conventional water Treatment processes. There are five
ways to remove inorganic contaminants; reverse osmosis, activated
alumina, ion exchange, activated carbon, and distillation.
Filtration through activated carbon will reduce the amount
of arsenic in drinking water from 40 - 70%. Anion exchange
can reduce it by 90 - 100%. Reverse Osmosis has a 90% removal
rate, and Distillation will remove 98%. If the arsenic is
present in organic form, it can be removed by oxidation of
the organic material and subsequent coagulation.
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- BACTERIA
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Source
- Bacteria are tiny organisms occurring naturally in water.
Not all types of bacteria are harmful. Many organisms found
in water are of no health concern since they do not cause
disease. Biological contamination may be separated into two
groups: (1) pathogenic (disease causing) and (2) non-pathogenic
(not disease causing). Pathogenic bacteria cause illnesses
such as typhoid fever, dysentery, gastroenteritis, infectious
hepatitis, and cholera. All water supplies should be tested
for biological content prior to use and consumption. E.Coli
(Escherichia Coli) is the coliform bacterial organism which
is looked for when testing the water. This organism is found
in the intestines and fecal matter of humans and animals.
If E.Coli is found in a water supply along with high nitrate
and chloride levels, it usually indicates that waste has contaminated
the supply from a septic system or sewage dumping, and has
entered by way of runoff, a fractured well casing, or broken
lines. If coliform bacteria is present, it is an indication
that disease causing bacteria may also be present. Four or
fewer colonies / 100 ml of coliforms, in the absence of high
nitrates and chlorides, implies that surface water is entering
the water system. If pathogenic bacteria is suspected, a sample
of water should be submitted to the Board of Health or US
EPA for bacteriological testing and recommendations. The most
common non-pathogenic bacteria found in water, is iron bacteria.
Iron bacteria can be readily identified by the red, feathery
floc which forms overnight at the bottom of a sample bottle
containing iron and iron bacteria.
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Treatment
- Bacteria can be treated by microfiltration, reverse osmosis,
ultrafiltration, or chemical oxidation and disinfection. Ultraviolet
sterilization will also kill bacteria; but turbidity, color,
and organic impurities interfere with the transmission of
ultraviolet energy and may decrease the disinfection efficiency
below levels to insure destruction. Ultraviolet Treatment
also does not provide residual bactericidal action, therefore
periodic flushing and disinfection must be done. Ultraviolet
sterilization is usually followed by 0.2 micron filtration
when dealing with high purity water systems. The most common
and undisputed method of bacteria destruction is chemical
oxidation and disinfection. Ozone injection into a water supply
is one form of chemical oxidation and disinfection. A residual
of 0.4 mg/l must be established and a retention time of four
minutes is required. Chlorine injection is the most widely
recognized method of chemical oxidation and disinfection.
Chlorine must be fed at 3 to 5 ppm to treat for bacteria and
a residual of 0.4 ppm of free chlorine must be maintained
for 30 minutes in order to meet US EPA standards. Reverse
Osmosis will remove 99+ % of the bacteria in a drinking water
system.
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- BARIUM
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Source
- Barium (Ba+2)is a naturally occurring alkaline earth metal
found primarily in the midwest. Traces of the element are
found in surface and ground waters. It can also be found in
oil and gas drilling muds, waste from coal fired power plants,
jet fuels, and automotive paints. Barium is highly toxic when
its soluble salts are ingested. The current MCL for Barium
is 2.0 mg/l.
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Treatment
- Sodium form cation exchange units (softeners) are very effective
at removing Barium. Reverse Osmosis is also extremely effective
in its removal, as well as Electrodialysis.
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- BENZENE
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Source
- Benzene, a byproduct of petroleum refining, is used as an
intermediate in the production of synthesized plastics, and
is also an additive in gasoline. Gasoline contains approximately
0.8 percent benzene by volume. Benzene is classified as a
volatile organic chemical (VOC) and is considered a carcinogen
by the US EPA. Benzene makes its way into water supplies from
leaking fuel tanks, industrial chemical waste, pharmaceutical
industry waste, or from run off of pesticides. The current
US EPA MCL for Benzene is 0.005 mg/l.
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Treatment
- Benzene can be removed with activated carbon. Approximately
1000 gallons of water containing 570 ppb of benzene can be
treated with 0.35 lbs of activated carbon, in other words;
94,300 gallons of water can be treated for every cubic foot
of carbon. The benzene must be in contact with the carbon
for a minimum of 10 minutes. If the required flow rate is
5 gpm, then 50 gallon of carbon is required; which converts
to approx. 7 cu. ft. The activated carbon must be replaced
when exhausted.
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- BICARBONATE
ALKALINITY
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Source
- The Bicarbonate (HCO3) ion is the principal alkaline constituent
in almost all water supplies. Alkalinity in drinking water
supplies seldom exceeds 300 mg/l. Bicarbonate alkalinity is
introduced into the water by CO2 dissolving carbonate-containing
minerals. Alkalinity control is important in boiler feed water,
cooling tower water, and in the beverage industry. Alkalinity
neutralizes the acidity in fruit flavors; and in the textile
industry, it interferes with acid dying. Alkalinity is known
as a "buffer."
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Treatment
- In the pH range of 5.0 to 8.0 there is a balance between
excess CO2 and bicarbonate ions. The bicarbonate alkalinity
can be reduced by removing the free CO2 through aeration.
The alkalinity can also be reduced by feeding acid to lower
the pH. At pH 5.0 there is only CO2
and 0
alkalinity. A strong base Anion Exchanger will also remove
alkalinity.
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- BORATE (BORON)
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Source
- Borate B(OH)4- is a compound of Boron. Most of the world's
boron is contained in sea water. Sodium borate occurs in arid
regions where inland seas once existed but have long since
evaporated. Boron is frequently present in fresh water supplies
in these same areas in the form of non-ionized boric acid.
The amount of boric acid is not limited by drinking water
standards, but it can be damaging to citrus crops if it is
present in irrigation water and becomes concentrated in the
soil.
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Treatment
- Boron behaves like silica when it is in an aqueous solution.
It can be removed with an Anion Exchanger or adsorbed utilizing
an Activated Carbon Filter.
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- BROMINE (BROMIDE)
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Source
- Bromine is found in sea water and exists as the bromide
ion at a level of about 65 mg/l. Bromine has been used in
swimming pools and cooling towers for disinfection, however
use in drinking water is not recommended. Ethylene bromide
is used as an anti-knock additive in gasoline, and methyl
bromide is a soil fumigant. Bromine is extremely reactive
and corrosive, and will produce irritation and burning to
exposed tissues. Over 0.05 mg/l in fresh water may indicate
the presence of industrial wastes, possibly from the use of
pesticides of biocides containing bromine. Bromide is extensively
used in the pharmaceutical industry, and occurs normally in
blood in the range of 1.5 to 50 mg/l.
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Treatment
- Reverse Osmosis will remove 93 -96 % of the bromide from
drinking water. Since bromine is a disinfectant, it along
with the disinfection by-products can also be removed with
Activated Carbon, Ultrafiltration, or Electrodialysis.
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- CADMIUM
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Source
- Cadmium enters the environment through a variety of industrial
operations, it is an impurity found in zinc. By-products from
mining, smelting, electroplating, pigment, and plasticizer
production can contain cadmium. Cadmium emissions come from
fossil fuel use. Cadmium makes its way into the water supplies
as a result of deterioration of galvanized plumbing, industrial
waste or fertilizer contamination.. The US EPA Primary Drinking
Water Standards lists Cadmium with a 0.005 mg/l MCL.
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Treatmen
- Cadmium can be removed from drinking water with a sodium
form cation exchanger (softener). Reverse Osmosis will remove
95 - 98 % of the cadmium in the water. Electrodialysis will
also remove the majority of the cadmium.
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- CALCIUM
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Source
- Calcium is the major component of hardness in water and
is usually in the range of 5 - 500 mg/l, as CaCO3 . Calcium
is derived from nearly all rock, but the greatest concentrations
come from limestone and gypsum. Calcium ions are the principal
cations in most natural waters. Calcium reduction is required
in treating cooling tower makeup. Complete removal is required
in metal finishing, textile operations, and boiler feed applications.
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Treatment
- Calcium, as with all hardness, can be removed with a simple
sodium form cation exchanger (softener). Reverse Osmosis will
remove 95
- 98 % of the calcium in the water. Electrodialysis and Ultrafiltration
also will remove calcium. Calcium can also be removed with
the hydrogen form cation exchanger portion of a deionizer
system.
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- CARBON DIOXIDE
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Source
- Free carbon dioxide (CO2) exists in varying amounts in most
natural water supplies. Most well waters will contain less
than 50 ppm. Carbon Dioxide in water yields an acidic condition.
Water (H2O) plus carbon dioxide (CO2) yields carbonic acid
(H2CO3). The dissociation of carbonic acid yields hydrogen
(H+) and bicarbonate alkalinity (HCO3). The pH value will
drop as the concentration of carbon dioxide increases, and
conversely will increase as the bicarbonate alkalinity content
increases.
- H2O + CO2 <====> H2CO3
<====> H+ + HCO3-
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Water with
a pH of 3.5 or below generally, contains mineral acids such
as sulfuric or hydrochloric acid. Carbon Dioxide can exist
in waters with pH values from 3.6 to 8.4, but will never be
present in waters having a pH of 8.5 or above. The pH value
is not a measurement of the amount of carbon dioxide in the
water, but rather the relationship of carbon dioxide and bicarbonate
alkalinity.
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Treatment
- Free CO2 can be easily dissipated by aeration. A two column
deionizer (consisting of a hydrogen form strong acid cation
and a hydroxide form strong base anion) will also remove the
carbon dioxide. The cation exchanger adds the hydrogen ion
(H+) which shifts the above equation to the left in favor
of water and carbon dioxide release. The anion resin removes
the carbon dioxide by actually removing the bicarbonate ion.
A forced draft degasifier placed between the cation and anion
will serve to blow off the CO2 before it reaches the anion
bed, thus reducing the capacity requirements for the anion
resin. The CO2 can be eliminated by raising the pH to 8.5
or above with a soda ash or caustic soda chemical feed system.
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- CARBON TETRACHLORIDE
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Source
- Carbon tetrachloride (CCl4) is a volatile organic chemical
(VOC), and is primarily used in the manufacture of chlorofluoromethane
but also in grain fumigants, fire extinguishers, solvents,
and cleaning agents. Many water supplies across the country
have been found to contain measurable amounts of VOC's. VOC's
pose a possible health risk because a number of them are probable
or known carcinogens. The detection of VOC's in a water supply
indicates that a pollution incident has occurred, because
these chemicals are man-made. See Volatile Organic Chemicals
for a complete listing. The US EPA has classified carbon tetrachloride
as a probable human carcinogen and established an MCL of 0.005
mg/l.
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Treatment
- Reverse Osmosis will remove 70 to 80% of the VOC's in drinking
water as will ultrafiltration and electrodialysis. Carbon
tetrachloride as well as the other volatile organic chemicals
(VOC's) can also be removed from drinking water with activated
carbon filtration. The adsorption capacity of the carbon will
vary with each type of VOC. The carbon manufacturers can run
computer projections on many of these chemicals and give an
estimate as to the amount of VOC which can be removed before
the carbon will need replacement.
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- CHLORIDE
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Source
- Chloride (Cl-1) is one of the major anions found in water
and are generally combined with calcium, magnesium, or sodium.
Since almost all chloride salts are highly soluble in water,
the chloride content ranges from 10 to 100 mg/l. Sea water
contains over 30,000 mg/l as NaCl. Chloride is associated
with the corrosion of piping because of the compounds formed
with it; for example, magnesium chloride can generate hydrochloric
acid when heated. Corrosion rates and the iron dissolved into
the water from piping increases as the sodium chloride content
of the water is increased. The chloride ion is instrumental
in breaking down passivating films which protect ferrous metals
and alloys from corrosion, and is one of the main causes for
the pitting corrosion of stainless steel. The SMCL (suggested
maximum contaminant level) for chloride is 250 mg/l which
is due strictly to the objectionable salty taste produced
in drinking water.
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Treatment
- Reverse Osmosis will remove 90 - 95% of the chlorides because
of it's salt rejection capabilities. Electrodialysis and distillation
are two more processes which can be used to reduce the chloride
content of water. Strong base Anion Exchanger which is the
later portion of a two column deionizer does an excellent
job at removing chlorides for industrial applications.
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- CHLORINE
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Source
- Chlorine is the most commonly used agent for the disinfection
of water supplies. Chlorine is a strong oxidizing agent capable
of reacting with many impurities in water including ammonia,
proteins, amino acids, iron, and manganese. The amount of
chlorine required to react with these substances is called
the chlorine demand. Liquid chlorine is sodium hypochlorite.
Household liquid bleach is 5-1/4% sodium hypochlorite. Chlorine
in the form of a solid is calcium hypochlorite. When chlorine
is added to water, a variety of chloro-compounds are formed.
An example of this would be when ammonia is present, inorganic
compounds known as chloramines are produced. Chlorine also
reacts with residual organic material to produce potentially
carcinogenic compounds, the Trihalomethanes (THM's): chloroform,
bromodichloromethane, bromoform, and chlorodibromomethane.
THM regulations has required that other oxidants and disinfectants
be considered in order to minimize THM formation. The other
chemical oxidants being examined are: potassium permanganate,
hydrogen peroxide, chloramines, chlorine dioxide, and ozone.
No matter what form of chlorine is added to water, hypochlorite,
hypochlorous acid, and molecular chlorine will be formed.
The reaction lowers the pH, thus making the water more corrosive
and aggressive to steel and copper pipe.
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Treatment
- Chlorinated water can be dosed with sulfite-bisulfite-sulfur
dioxide or passed through a activated carbon filter. Activated
carbon will remove 880,000 ppm of free chlorine per cubic
foot of media.
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- CHROMIUM
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Source
- Chromium is found in drinking water as a result of industrial
waste contamination. The occurrence of excess chromium is
relatively infrequent. Proper tests must be run on the water
supply to determine the form of the chromium present. Trivalent
chromium (Cr=3 ) is slightly soluble in water, and is considered
essential in man and animals for efficient lipid, glucose,
and protein metabolism. Hexavalent chromium (Cr=6 ) on the
other hand is considered toxic. The US EPA classifies chromium
as a human carcinogen. The current Drinking Water Standards
MCL is .005 mg/l.
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Treatment
- Trivalent chromium (Cr+3)can be removed with strong acid
cation resin regenerated with hydrochloric acid. Hexavalent
chromium (Cr+6)on the other hand requires the utilization
of a strong base anion exchanger which must be regenerated
with caustic soda (sodium hydroxide) NaOH. Reverse Osmosis
can effectively reduce both forms of chromium by 90 to 97%.
Distillation will also reduce chromium.
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- COLOR
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Source
- Color in water is almost always due to organic material
which is usually extracted from decaying vegetation. Color
is common in surface water supplies, while it is virtually
non-existent in spring water and deep wells. Color in water
may also be the result of natural metallic ions (iron and
manganese). A yellow tint to the water indicates that humic
acids are present, referred to as "tannins". A reddish
color would indicate the presence of precipitated iron. Stains
on bathroom fixtures and on laundry are often associated with
color also. Reddish-brown is ferric hydroxide (iron) which
will precipitate when the water is exposed to air. Dark brown
to black stains are created by manganese. Excess copper can
create blue stains.
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Treatment
- Color is removed by chemical feed, retention and filtration.
Activated carbon filtration will work most effectively to
remove color in general. Anion scavenger resin will remove
tannins, but must be preceded by a softener or mixed with
fine mesh softener resin. See the headings Iron, Manganese,
and Copper for information their removal or reduction.
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- COPPER
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Source
- Copper (Cu+3) in drinking water can be derived from rock
weathering, however the principal Sources are the corrosion
of brass and copper piping and the addition of copper salts
when treating water supplies for algae control. Copper is
required by the body for proper nutrition. Insufficient amounts
of copper leads to iron deficiency. However, high doses of
copper can cause liver damage or anemia. The taste threshold
for copper in drinking water is 2 - 5 mg/l. The US EPA has
proposed a maximum contaminant level (MCL) of 1.3 mg/l for
copper.
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Treatment
- Copper can be reduced or removed with sodium form strong
acid cation resin (softener) dependent on the concentration.
If the cation resin is regenerated with acid performance will
be enhanced. Reverse osmosis or electrodialysis will remove
97 - 98 % of the copper in the water supply. Activated carbon
filtration will also remove copper by adsorption.
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- CRYPTOSPORIDIUM
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Source
- Cryptosporidium is a protozoan parasite which exists as
a round oocyst about 4 to 6 microns in diameter. Oocysts pass
through the stomach into the small intestine where it's sporozoites
invade the cell lining of the gastrointestinal tract. Symptoms
of infection include diarrhea, cramps, nausea, and low grade
fever.
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Treatment
- Filtration is the most effective Treatment for protozoan
cysts. Cartridge POU filters rated at 0.5 micron are designed
for this purpose.
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- CYANIDE
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Source
- Cyanide (CN-) is extremely toxic and is not commonly found
at significant levels in drinking water. Cyanide is normally
found in waste water from metal finishing operations. The
US EPA has not classified cyanide as a carcinogen because
of inadequate data. No MCL level established or even proposed.
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Treatment
- Chlorine feed, retention, and filtration will break down
the cyanide. Reverse Osmosis or Electrodialysis will remove
90 - 95 % of it.
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- FLUORIDE
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Source
- Fluoride (F+) is a common constituent of many minerals.
Municipal water Treatment plants commonly add fluoride to
the water for prevention of tooth decay, and maintain a level
of 1.5 - 2.5 mg/l. Concentrations above 5 mg/l are detrimental
to tooth structure. High concentrations are contained in waste
water from the manufacture of glass and steel, as well as
from foundry operations. Organic fluorine is present in vegetables,
fruits, and nuts. Inorganic fluorine, under the name of sodium
fluoride, is a waste product of aluminum and is used in some
rat poisons. The MCL established for drinking water by the
US EPA is 4 mg/l.
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Treatment
- Fluoride can be reduced by anion exchange. Adsorption by
calcium phosphate, magnesium hydroxide or activated carbon
will also reduce the fluoride content of drinking water. Reverse
osmosis will remove 93 - 95 % of the fluoride.
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- GIARDIA
LAMBLIA
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Source
- Giardia is a protozoan which can exist as a trophozoite,
usually 9 to 21 mm long, or as an ovoid cyst, approximately
10 mm long and 6 mm wide. Protozoans are unicellular and colorless
organisms that lack a cell wall. When Giardia are ingested
by humans, symptoms include diarrhea, fatigue, and cramps.
The US EPA has a Treatment technique in effect for Giardia.
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Treatment
- Slow sand filtration or a diatomaceous earth filter can
remove up to 99 % of the cysts when proper preTreatment is
utilized. Chemical oxidation - disinfection, Ultrafiltration,
and reverse osmosis all effectively remove Giardia cysts.
Ozone appears to be very effective against the cysts when
utilized in the chemical oxidation - disinfection process
instead of chlorine. The most economical and widely used method
of removing Giardia is mechanical filtration. Because of the
size of the parasite, it can easily be removed with precoat,
solid block carbon, ceramic, pleated membrane, and spun wrapped
filter cartridges.
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- HARDNESS
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Source - Hard water
is found over 80% of the United States. The hardness of a
water supply is determined by the content of calcium and magnesium
salts. Calcium and magnesium combine with bicarbonates, sulfates,
chlorides, and nitrates to form these salts. The standard
domestic measurement for hardness is grains per gallon (gpg)
as CaCO3 . Water having a hardness content less than 0.6 gpg
is considered commercially soft. The calcium and magnesium
salts which form hardness are divided into two categories:
1) Temporary Hardness (containing carbonates), and 2) Permanent
Hardness (containing non-carbonates). Below find listings
of the various combinations of permanent and temporary hardness
along with their chemical formula and some information on
each.
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- *** Temporary Hardness Salts ***
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Calcium Carbonate (CaCO3)
- Known as limestone, rare in water supplies. Causes alkalinity
in water.
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Calcium Bicarbonate [Ca(HCO3)2]
- Forms when water containing CO2 comes in contact with limestone.
Also causes alkalinity in water. When heated CO2 is released
and the calcium bicarbonate reverts back to calcium carbonate
thus forming scale.
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Magnesium Carbonate (MgCO3)
- Known as magnesite with properties similar to calcium carbonate.
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Magnesium Bicarbonate [Mg(HCO3)2]
- Similar to calcium bicarbonate in its properties.
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*** Permanent Hardness Salts
***
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Calcium Sulfate (CaSO4) -
Know as gypsum, used to make plaster of paris. Will precipitate
and form scale in boilers when concentrated.
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Calcium Chloride (CaCl2) -
Reacts in boiler water to produce a low pH as follows: CaCl2
+ 2HOH ==> Ca(OH)2 + 2HCl
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Magnesium Sulfate (MgSO4)
- Commonly known as epsom salts, may have laxative effect
if great enough quantity is in the water.
- Magnesium Chloride (MgCl2) - Similar in properties
to calcium chloride.
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Sodium salts are also found
in household water supplies, but they are considered harmless
as long as they do not exist in large quantities. The US EPA
currently has no national policy with respect to the hardness
or softness of public water supplies.
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Treatment
- Softeners can remove compensated hardness up to a practical
limit of 100 gpg. If the hardness is above 30 gpg or the sodium
to hardness ratio is greater than 33%, then economy salt settings
can not be used. If the hardness is high, then the sodium
will be high after softening, and may require that reverse
osmosis be used for producing drinking water.
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- HYDROGEN SULFIDE
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Source - Hydrogen Sulfide
(H2S) is a gas which imparts its "rotten egg" SULFIDE
odor to water supplies. Such waters are distasteful for drinking
purposes and processes in practically all industries. Most
sulfur waters contain from 1 to 5 ppm of hydrogen sulfide.
Hydrogen sulfide can interfere with readings obtained from
water samples. It turns hardness and pH tests gray, and makes
iron tests inaccurate. Chlorine bleach should be added to
eliminate the H2S odor; then the hardness, pH and iron tests
can be done. Hydrogen sulfide can not be tested in a lab,
it must be done in the field. Hydrogen sulfide is corrosive
to plumbing fixtures even at low concentrations. H2S fumes
will blacken or darken painted surfaces, giving them a "smoked"
appearance.
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Treatment
- H2S requires chlorine to be fed in sufficient quantities
to eliminate it, while leaving a residual in the water (3
ppm of chlorine is required for each ppm of hydrogen sulfide).
Activated carbon filtration may then be installed to remove
the excess chlorine.
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- IRON
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Source - Iron occurs
naturally in ground waters in three forms, Ferrous Iron (clear
water iron), Ferric Iron (red water iron), and Heme Iron (organic
iron). Each can exist alone or in combination with the others.
Ferrous iron, or clear water iron as it is sometimes called,
is ferrous bicarbonate. The water is clear when drawn but
when turns cloudy when it comes in contact with air. The air
oxidizes the ferrous iron and converts it to ferric iron.
Ferric iron, or ferric hydroxide, is visible in the water
when drawn; hence the name "red water iron". Heme
iron is organically bound iron complexed with decomposed vegetation.
The organic materials complexed with the iron are called tannins
or lignins. These organics cause the water to have a weak
tea or coffee color. Certain types of bacteria use iron as
an energy Source. They oxidize the iron from its ferrous state
to its ferric state and deposit it in the slimy gelatinous
material which surround them. These bacteria grow in stringy
clumps and are found in most iron bearing waters.
-
-
Treatment
- Ferrous iron (clear water iron) can be removed with a softener
provided it is less than 0.5 ppm for each grain of hardness
and the pH of the water is greater than 6.8. If the ferrous
iron is more than 5.0 ppm, it must be converted to ferric
iron by contact with a oxidizing agent such as chlorine, before
it can be removed by mechanical filtration. Ferric iron (red
water iron) can simply be removed by mechanical filtration.
Heme iron can be removed by an organic scavenger anion resin,
or by oxidation with chlorine followed by mechanical filtration.
Oxidizing agents such as chlorine will also kill iron bacteria
if it is present.
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-
-
-
- LEAD
-
Source - Lead (Pb+2)
found in fresh water usually indicates contamination from
metallurgical wastes or from lead-containing industrial poisons.
Lead in drinking water is primarily from the corrosion of
the lead solder used to put together the copper piping. Lead
in the body can cause serious damage to the brain, kidneys,
nervous system, and red blood cells. The US EPA considers
lead to be a highly toxic metal and a major health threat.
The current level of lead allowable in drinking water is 0.05
mg/l.
-
-
Treatment
- Lead can be reduced considerably with a water softener.
Activated carbon filtration can also reduce lead to a certain
extent. Reverse Osmosis can remove 94 to 98 % of the lead
in drinking water at the point-of-use. Distillation will also
remove the lead from drinking water.
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-
-
-
- LEGIONELLA
-
Source - In July 1976,
there was an outbreak of pneumonia effecting 221 people attending
the annual Pennsylvania American Legion convention at the
Bellvue-Stratford Hotel in Philadelphia. Out of the 221 people
infected, 34 died. It wasn't until December 1977 that microbiologists
were able to isolate a bacterium from the autopsy of the lung
tissue of one of the legionnaires. The bacterium was named
"Legionella pneumophila" (Legionella in honor of
the American Legion, and pneumophila which is Greek for "lung-loving")
and was found to be completely different from other bacteria.
Unlike patients with other pneumonias, patients with legionnaire's
disease often have severe gastrointestinal symptoms, including
diarrhea, nausea, and vomiting. The US EPA has not set a MCL
(maximum contamination level) for Legionella, instead it has
outlined the Treatment method which must be followed and the
MCLG is 0 mg/l.
-
-
Treatment
- Chemical oxidation-disinfection followed by retention, then
filtration could be used. Since Legionella is a bacteria,
Reverse osmosis or Ultrafiltration are the preferred removal
techniques.
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-
-
- MAGNESIUM
-
Source - Magnesium
(Mg+2) hardness is usually approximately 33% of the total
hardness of a particular water supply. Magnesium is found
in many minerals, including dolomite, magnesite, and many
types of clay. It is in abundance in sea water where its'
concentration is five (5) times the amount of calcium. Magnesium
carbonate is seldom a major component of in scale. However,
it must be removed along with calcium where soft water is
required for boiler make-up, or for process applications.
-
-
Treatment
- Magnesium may be reduced to less than 1 mg/l with the use
of a softener or cation exchanger in hydrogen form. Also see
"Hardness".
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-
-
-
- MANGANESE
-
Source - Manganese
(Mn+4, Mn+2) is present in many soils and sediments as well
as in rocks whose structures have been changed by heat and
pressure. It is used in the manufacture of steel to improve
corrosion resistance and hardness. Manganese is considered
essential to plant and animal life and can be derived from
such foods as corn, spinach, and whole wheat products. It
is known to be important in building strong bones and may
be beneficial to the cardiovascular system. Manganese may
be found in deep well waters at concentrations as high as
2 - 3 mg/l. It is hard to treat because of the complexes it
can form which are dependent on the oxidation state, pH, bicarbonate-carbonate-OH
ratios, and the presence of other minerals, particularly iron.
Concentrations higher than 0.05 mg/l cause manganese deposits
and staining of clothing and plumbing fixtures. The stains
are dark brown to black in nature. The use of chlorine bleach
in the laundry will cause the stains to set. The chemistry
of manganese in water is similar to that of iron. High levels
of manganese in the water produces an unpleasant odor and
taste. Organic materials can tie up manganese in the same
manner as they do iron, therefore destruction of the organic
matter is a necessary part of manganese removal.
-
-
Treatment
- Removal of manganese can be done by ion exchange (sodium
form cation - softener) or chemical oxidation - retention
- filtration. Removal with a water softener dictates that
the pH be 6.8 or higher and is beneficial to use countercurrent
regeneration with brine make-up and backwash utilizing soft
water. It takes 1 ppm of oxygen to treat 1.5 ppm of manganese.
Greensand filter with potassium will remove up to 10 ppm if
pH is above 8.0. Birm filter with air injection will reduce
manganese if pH is 8.0 to 8.5. Chemical feed (chlorine, potassium
permanganate, or hydrogen peroxide) followed by 20 minutes
retention and then filtered with birm, greensand, carbon,
or Filter Ag will also remove the manganese.
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-
-
- MERCURY
-
Source - Mercury (Hg)
is one of the least abundant elements in the earth's crust.
It exists in two forms, an inorganic salt or an organic compound
(methyl mercury). Mercury detected in drinking water is of
the inorganic type. Organic mercury inters the food chain
through fish and comes primarily from industrial chemical
manufacturing waste or from the leaching of coal ash. If inorganic
mercury inters the body, it usually settles in the kidneys.
Whereas organic mercury attacks the central nervous system.
The MCL (maximum contamination level) for mercury set by the
US EPA is 0.002 mg/l.
-
-
Treatment
- Activated carbon filtration is very effective for the removal
of mercury. Reverse osmosis will remove 95 - 97 % of it.
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-
-
-
- METHANE
-
Source - Methane (CH4),
often called marsh gas, is the primary component of natural
gas. It is commonly found where land fills once existed and
is generated from decaying of plants or other carbon based
matter. It can also be found in and around oil fields. Methane
is colorless, odorless, nearly invisible, highly flammable,
and often found in conjunction with other gases such as hydrogen
sulfide. Even though methane gas gives water a milky appearance
which makes it aesthetically unpleasant, there are no known
health effects.
-
-
Treatment
- Aeration or degasification is the only way to eliminate
the problem of methane gas. Venting the casing and/or the
cap of the well will reduce the problem of methane in the
water, but may not completely eliminate it. Another method
is to provide an atmospheric holding tank where the methane
laden water can be vented to allow the gas to dissipate. This
method may not be 100% effective either. An aerator or degasifier
is the proper piece of equipment to utilize for the removal
of methane. Water is introduced through the top, sometimes
through spray nozzles, and allowed to percolate through a
packing material. Air is forced in the opposite direction
to the water flow. The water is then collected in the bottom
of the unit and repressurized.
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-
Alert
from U.S. EPA on this Item.
- MTBE
-
Source - MTBE (methyl
tertiary butyl ether) is a gasoline additive mandated by the
Federal Clean Air Act to reduce emissions from automobiles.
However, it has been found to be a "NEW" and
major source of groundwater contamination. MTBE has a
noticeable odor at 20 to 40 ppb (parts per billion), which
the U.S. EPA says is about 20,000 to 100,000 times lower than
the range of exposure levels at which health effects were
observed in rodent tests.
-
-
Treatment
- MTBE is a light, or low molecular weight organic and highly
soluble in water. At this time, air stripping and granular
activated carbon are the most effective technologies for removal
of MTBE. Carbon rated for the removal of VOC's (Volatile Organic
Chemicals) or chloroform is recommended. For MTBE concentrations
greater than 100 parts per billion (ppb) in water, it is recommended
to pretreat with an atmospheric air stripping system with
re-pressurization prior to activated carbon absorption.
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-
-
NICKEL
-
Source - Nickel (Ni+2)
is common, and exists in approximately 85% of the water supplies,
and is usually around 1 ppb (part per billion). The US EPA
has classified nickel as a possible human carcinogen based
on inhalation exposure. Nickel has not been shown to be carcinogenic
via oral exposure. No MCLG (maximum contamination level goal)
has been proposed.
-
-
Treatment
- Nickel behaves the same as iron, and can be removed by a
strong acid cation exchanger. Activated carbon filtration
can be used to reduce the amount of nickel in drinking water,
but may not remove it all. Reverse osmosis will remove 97
- 98 % of the nickel from drinking water.
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-
NITRATE
-
Source - Nitrate (NO3)
comes into water supplies through the nitrogen cycle rather
than via dissolved minerals. It is one of the major ions in
natural waters. Most nitrate that occurs in drinking water
is the result of contamination of ground water supplies by
septic systems, feed lots, and agricultural fertilizers. Nitrate
is reduced to nitrite in the body. The US EPA's MCL for nitrate
is 10 mg/l.
-
-
Treatment
- Reverse Osmosis will remove 92 - 95% of the nitrates and/or
nitrites. Anion exchange resin will also remove both as will
distillation.
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-
NITRITE
-
Source - Nitrites are
not usually found in drinking water supplies at concentrations
above 1 or 2 mg/l (ppm). Nitrates are reduced to nitrites
in the saliva of the mouth and upper GI tract. This occurs
to a much greater degree in infants than in adults, because
of the higher alkaline conditions in their GI tract. The nitrite
then oxidizes hemoglobin in the blood stream to methemoglobin,
thus limiting the ability of the blood to carry oxygen throughout
the body. Anoxia (an insufficiency of oxygen) and death can
occur. The US EPA has established the MCL (maximum contaminant
level) for nitrite at 1 mg/l.
-
-
Treatment
- Nitrites are removed in the same manner as nitrates; reverse
osmosis, anion exchange, or distillation. See Nitrate - Treatment.
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-
ODOR
-
Source - Taste and
odor problems of many different types can be encountered in
drinking water. Troublesome compounds may result from biological
growth or industrial activities. The tastes and odors may
be produced in the water supply, in the water Treatment plant
from reactions with Treatment chemicals, in the distribution
system, and/or in the plumbing of consumers. Tastes and odors
can be caused by mineral contaminants in the water, such as
the "salty" taste of water when chlorides are 500
mg/l or above, or the "rotten egg" odor caused by
hydrogen sulfide. Odor in the drinking water is usually caused
by blue-green algae. Moderate concentrations of algae in the
water can cause it to have a "grassy", "musty"
or "spicy" odor. Large quantities can cause the
water to have a"rotten", "septic", "fishy"
or "medicinal" odor. Decaying vegetation is probably
the most common cause for taste and odor in surface water
supplies. In treated water supplies chlorine can react with
organics and cause odor problems. Odor is listed in the Secondary
Drinking Water Standards by the US EPA. The contaminant effects
are strictly aesthetic and a suggested Threshold Odor Number
(TON) of 3 is recommended.
-
-
Treatment
- Odor can be removed by oxidation-reduction or by activated
carbon adsorption. Aeration can be utilized if the contaminant
is in the form of a gas, such as H2S (hydrogen sulfide). Chlorine
is the most common oxidant used in water Treatment, but is
only partially effective on taste and odor. Potassium permanganate
and oxygen are also only partially effective. Chloramines
are not at all effective for the Treatment of taste and odor.
The most effective oxidizers for treating taste and odor,
are chlorine dioxide and ozone. Activated carbon has an excellent
history of success in treating taste and odor problems. The
life of the carbon depends on the presence of organics competing
for sites and the concentration of the odor causing compound.
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-
ORGANICS
-
Source - Organic matter
makes up a significant part of the soil, therefore water soluble
organic compounds are present in all water supplies. Organic
matter is reported on a water analysis as carbon, as it is
in the TOC (total organic carbon) determination. The following
is a list of organics which is regulated under the Safe Drinking
Water Act of 1986.
-
-
| Endrin |
1,1,2-Trichloroethane |
| Lindane |
2,3,7,8-Tetrachlorodibenzodioxin
(dioxin) |
| Methoxychlor |
Vydate |
| Toxaphene |
Simazine |
| 2,4-D |
Polynuclear
aromatic hydrocarbons (PAH) |
| 2,4,5-TP |
| Polychlorinated
biphenyls (PCB) |
|
| Aldicarb |
Phthalates |
| Chlordane |
Atrazine |
| Dalapon |
Acrylamide |
| Diquat |
Dibromochloropropane
(DBCP) |
| Endothall |
1,2-Dichloropropane |
| Glyphosate |
Pentachlorophenol |
| Carbofuran |
Pichloram |
| Alachlor |
Dinoseb |
| Epichlorohydrin |
Ethylene
dibromide (EDB) |
| Toluene |
Dibromomethane |
| Adipates |
Xylene |
| Hexachlorocyclopentadiene |
|
-
- Organics come from three major Sources:
- The breakdown of naturally occurring organic
materials.
- Domestic and commercial chemical wastes.
- Chemical reactions that occur during water
Treatment processes.
-
-
The first Source is
comprised of humic materials, microorganisms, and petroleum-based
aliphatic and aromatic hydrocarbons. The second source,
derived from domestic and commercial chemical wastes include
wastewater discharges, agricultural runoff, urban runoff,
and leaching from contaminated soils. Organic contaminants
comprising the third source which are formed during
water Treatment include disinfection by-products such as THM's
(Trihalomethanes), or undesirable components of piping assembly
such as joint adhesives.
-
-
Treatment
- Activated carbon is generally used to remove organics, color,
and taste-and-odor causing compounds. The contact time and
service flow rate dictate the size of the carbon filter. When
removing organics, restrict flow rates to 2 gpm per square
foot of the filter bed. Reverse Osmosis will remove 98 to
99% of the organics in the water. Ultrafiltration (UF) and
nanofiltration (NF) have both been proven to remove organics.
Anion exchange resin also retains organics, but periodically
needs cleaning.
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-
-
-
- PESTICIDES
-
Source - Pesticides
are common synthetic organic chemicals (SOCs). Pesticides
reach surface and well water supplies from the runoff in agricultural
areas where they are used. Certain pesticides are banned by
the government because of their toxicity to humans or their
adverse effect on the environment. Pesticides usually decompose
and break down as they perform their intended function. Low
levels of pesticides are found where complete break down does
not occur. There is no US EPA maximum contamination level
(MCL) for pesticides as a total, each substance is considered
separately.
-
-
Treatment
- Activated carbon filtration is
the most effective way to remove organics whether synthetic
(like pesticides) or natural. Ultrafiltration will also remove
organic compounds. Reverse Osmosis will remove 97 - 99% of
the pesticides.
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-
-
-
- pH
-
Source - The term "pH"
is used to indicate acidity or alkalinity of a given solution.
It is not a measure of the quantity of acid or alkali, but
rather a measure of the relationship of the acid to the alkali.
The pH value of a solution describes its hydrogen-ion activity.
The pH scale ranges between
- 0 and 14.
-
- Acidic [ 0 ]=========[ 7 ]==========[ 14 ] Alkaline
-
-
-
Typically all natural waters
fall within the range of 6.0 to 8.0 pH. A value of 7.0 is
considered to be a neutral pH. Values below 7.0 are acidic
and values above 7.0 are alkaline. The pH value of water will
decrease as the content of CO2 increases, and will increase
as the content of bicarbonate alkalinity increases. The ratio
of carbon dioxide and bicarbonate alkalinity (within the range
of 3.6 to 8.4) is an indication of the pH value of the water.
Water with a pH value of 3.5 or below, generally contains
mineral acids such as sulfuric or hydrochloric acid.
-
-
Treatment
- The pH can be raised by feeding sodium
hydroxide (caustic soda), sodium carbonate (soda ash), sodium
bicarbonate, potassium hydroxide, etc. into the water stream.
A neutralizing filter containing Calcite (calcium carbonate
- CaCO3 ) and/or Corosex (magnesium oxide - MgO) will combat
low pH problems, if within the range of 5 to 6. the peak flow
rate of a neutralizing filter is 6 gpm / sq. ft. Downflow
filters require frequent backwashing is required to prevent
"cementing of the bed". A 50 - 50 mix of the two
seems to provide the best all around results. Upflow neutralizers
don't experience the problem of "cementing" of the
bed.
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-
-
-
- POTASSIUM
- Source - Potassium (K+) is an alkaline
metal closely related to sodium. It is seldom that one sees
it analyzed separately on a water analysis. Potassium is not
a major component in public or industrial water supplies. Potassium
is, however, essential in a well balanced diet and can be found
in fruits such as bananas.
-
- Treatment
- Potassium can be removed by a cation exchange resin, usually
in the form of a softener. It can also be reduced by 94 - 97%
utilizing Electrodialysis or reverse osmosis.
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-
-
- RADIUM
-
Source - Radium (Ra)
is a radioactive chemical element which can be found in very
small amounts in pitchblende and other uranium minerals. It
is used in the Treatment of cancer and some skin diseases.
Radium 226 and radium 228 are of most concern when found in
drinking water because of the effects on the health of individuals.
Radium 228 causes bone sarcomas. Radium 226 induces carcinomas
in the head. Radioactivity in water can be naturally occurring
or can be from man-made contamination. Radiation is generally
measured in curies (Ci). One curie equals 3.7 x 1010 nuclear
transformations per second. A picocurie (pCi) equals 10-12
curies. The US EPA has set the MCL (maximum contamination
level) for radium 226 and 228 at 5 pCi/L under the NIPDWR
(national interim primary drinking water regulations).
-
-
Treatment
- Radium can be removed by sodium for
cation exchange resin in the form of a water softener. Reverse
Osmosis will remove 95 - 98% of any radioactivity in the drinking
water.
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-
-
-
- RADON
-
Source - Radon (Rn)
is a radioactive gaseous chemical element formed in the atomic
disintegration of radium. Radon 222 is one of the radionuclides
of most concern when found in drinking water. It is a naturally
occurring isotope, but can also come from man-made Sources.
All radionuclides are considered carcinogens, but the organs
they target vary. Since radon 222 is a gas, it can be inhaled
during showers or while washing dishes. There is a direct
relationship between radon 222 and lung cancer.Under the NIPDWR
(national interim primary drinking water regulations), the
MCL (maximum contamination level) for radon 222 is set at
15 pCi/L (see radium for explanation of how radiation is measured).
-
-
Treatment
- Radon is easily removed by aeration,
since it is a gas. Carbon filtration is also very effective
in removing radon.
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-
-
-
- SELENIUM
-
Source - Selenium (Se)
is essential for human nutrition, with the majority coming
from food. The concentration found in drinking water is usually
low, and comes from natural minerals. Selenium is also a by-product
of copper mining / smelting. It is used in photoelectric devises
because it's electrical conductivity varies with light. Naturally
occurring selenium compounds have not been shown to be carcinogenic
in animals. However, acute toxicity caused by high selenium
intake has been observed in laboratory animals and in animals
grazing in areas where high selenium levels exist in the soil.
The US EPA has established the MCL for selenium at 0.05 mg/l.
-
-
Treatment
- Anion exchange can reduce the amount
of selenium in drinking water by 60 - 95%. Reverse Osmosis
is excellent at reduction of selenium.
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-
-
-
- SILICA
-
Source - Silica (SiO2)
is an oxide of silicon, and is present in almost all minerals.
It is found in surface and well water in the range of 1 -
100 mg/l. Silica is considered to be colloidal in nature because
of the way it reacts with adsorbents. A colloid is a gelatinous
substance made up of non-diffusible particles that remain
suspended in a fluid medium. Silica is objectionable in coo |